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Issue 69, 2017
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From aqueous speciation to supramolecular assembly in alkaline earth-uranyl polyoxometalates

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Abstract

The interplay between aqueous alkaline earth (Ca, Sr, Ba) polycationic speciation and uranyl–peroxide polyoxometalate self-assembly and evolution is described here using solution (Raman and X-ray scattering) and solid-state (microscopy, X-ray diffraction) characterization. Supramolecular assembly of Sr-encapsulated and decorated polyanions and polycations yields the fourth largest inorganic unit cell reported from single-crystal X-ray diffraction.

Graphical abstract: From aqueous speciation to supramolecular assembly in alkaline earth-uranyl polyoxometalates

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Publication details

The article was received on 12 Jul 2017, accepted on 04 Aug 2017 and first published on 15 Aug 2017


Article type: Communication
DOI: 10.1039/C7CC05357F
Citation: Chem. Commun., 2017,53, 9550-9553
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    From aqueous speciation to supramolecular assembly in alkaline earth-uranyl polyoxometalates

    C. Falaise, S. M. Hickam, P. C. Burns and M. Nyman, Chem. Commun., 2017, 53, 9550
    DOI: 10.1039/C7CC05357F

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